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| 1 | A Novel Integrated Method for Large-Scale Detection, Identification, and Quantification of Widely Targeted Metabolites: Application in the Study of Rice Metabolomics显示文摘液体 chromatographymass spectrometry (最小公倍数) 基于 metabolomics 被 MS 2 的构造便于光谱从全部的扫描 ESI MS/MS 数据的标签(MS2T ) 图书馆,和广泛地指向的 metabolomics methodusing MS/MS 数据的发展从真标准聚在一起。在这份报告,称为逐步的多重离子 monitoring-enhancedproduct 离子(逐步的 MIMEPI ) 的新奇策略被开发构造 MS2T 图书馆,逐步的 MIM 在被用作调查 scansto 触发 EPI 的获得。698 的一个全部的数字(几乎) 有 MS 2 系列的非冗余的代谢物被获得,哪个 135 代谢物被识别 / 注解。集成数据从我们的 MS2T libraryand 收集了监视的另外的可得到的多重反应(MRM ) 信息,一个广泛地指向的 metabolomics 方法被开发 toquantify 277 代谢物,包括一些植物激素。在米饭叶的脱水回答和自然变化 ofthese 代谢物的评估不仅与代谢物 suchas 血清素衍生物建议了 abscisic 酸(骆驼毛的织物)的协调规定, polyamine 在干旱应力下面结合,而且为 indica 和装饰用的梨树米饭亚种的辨别作为潜在的标记揭示了一些 C-glycosylated 黄酮。新 MS2T 图书馆构造和广泛地指向的 metabolomics 策略能被用作工具 forrice 功能的 genomics.Key 词: | Wei Chen Liang Gong Zilong GUO Wensheng Wang Hongyan Zhang Xianqing Liu SibinYu Lizhong Xiong Jie Luo | 2013 | Molecular Plant2013，6，6： | 162 |
| 2 | Genome-Wide Association Studies of Image Traits Reveal Genetic Architecture of Drought Resistance in Rice显示文摘理解植物怎么对干旱作出回应能有益于繁殖的干旱抵抗(医生) 。用一台非破坏性的 phenotyping 设备,为 507 米饭就职的 51 个基于图象的特点(i 特点) 被提取。这些 i 特点能被用来监视干旱回答 ? 并且高评估医生可遗传性和这些特点的大变化在自然人口在干旱应力下面被观察。染色体宽的协会研究(GWAS )?i 特点和传统的医生特点识别了 470 协会 loci,某包含知道医生相关的基因。这 470 loci, 443 loci (94%) 用 i 特点被识别, 437 loci (93%) 与以前报导的医生相关的量的特点 loci,和 313 loci (66.6%)co 局部性被 GWAS reproducibly 在不同的年里识别。协会网络,基于 GWAS 建立了结果,揭示中心 i 特点和中心 loci。这表明把的可行性和必要性复杂医生特点进可继承、简单的 i 特点。作为原则的证明,我们说明了这条综合途径的力量以前识别 unreported 医生相关的基因。OsPP15 与中心 i 特点被联系,并且它在医生的角色被基因转变实验证实。而且, i 特点能被用于医生连接分析,并且 69 个 i 特点地点协会被 recombinant 的 GWAS 和连接分析识别生来的线人口。最后,我们证实了 i 特点的关联在这个领域里搀。我们的学习为医生为原因的基因的基因解剖和发现提供一条有希望的新奇途径。 | Zilong Guo Wanneng Yang Yu Chang Xiaosong Ma Haifu Tu Fang Xiong Ni Jiang Hui Feng Chenglong Huang Peng Yang Hu Zhao Guoxing Chen Hongyan Liu Lijun Luo Honghong Hu Qian Liu Lizhong Xiong | 2018 | Molecular Plant2018，11，6： | 21 |
| 3 | Cancer incidence and mortality in Shandong province,2012显示文摘Objective: Population-based cancer registration data in 2012 from all available cancer registries in Shandong province were collected by Shandong Center for Disease Control and Prevention(SDCDC). SDCDC estimated the numbers of new cancer cases and cancer deaths in Shandong province with compiled cancer incidence and mortality rates.Methods: In 2015, there were 21 cancer registries submitted data of cancer incidence and deaths occurred in 2012. All the data were checked and evaluated based on the National Central Cancer Registry(NCCR) criteria of data quality. Qualified data from 15 registries were used for cancer statistics analysis as provincial estimation. The pooled data were stratified by area(urban/rural), gender, age group(0, 1-4, 5-9, 10-14, …, 85+ years) and cancer type. New cancer cases and deaths were estimated using age-specific rates and corresponding provincial population in 2012. The Chinese census data in 2000 and Segi's population were applied for age-standardized rates. All the rates were expressed per 100,000 person-year.Results: Qualified 15 cancer registries(4 urban and 11 rural registries) covered 17,189,988 populations(7,486,039 in urban and 9,703,949 in rural areas). The percentage of cases morphologically verified(MV%) and death certificate-only cases(DCO%) were 66.12% and 2.93%, respectively, and the mortality to incidence rate ratio(M/I) was 0.60. A total of 253,060 new cancer cases and 157,750 cancer deaths were estimated in Shandong province in 2012. The incidence rate was 263.86/100,000(303.29/100,000 in males, 223.23/100,000 in females), the age-standardized incidence rates by Chinese standard population(ASIRC) and by world standard population(ASIRW) were 192.42/100,000 and 189.50/100,000 with the cumulative incidence rate(0-74 years old) of 22.07%. The cancer incidence, ASIRC and ASIRW in urban areas were 267.64/100,000, 195.27/100,000 and 192.02/100,000 compared to 262.32/100,000, 191.26/100,000 and 188.48/100,000 in rural areas, respectively. The cancer mortality was 164.47/100,000(207.42/100,000 in males, 120.23/100,000 in females), the age-standardized incidence rates by Chinese standard population(ASMRC) and by world standard population(ASMRW) were 117.54/100,000 and 116.90/100,000, and the cumulative mortality rate(0-74 years old) was 13.53%. The cancer mortality, ASMRC and ASMRW were 141.59/100,000, 101.17/100,000 and 100.33/100,000 in urban areas, and 173.79/100,000, 124.20/100,000 and 123.64/100,000 in rural areas, respectively. Cancers of the lung, stomach, liver, esophagus, colorectum, female breast, brain, leukemia, bladder and pancreas were the most common cancers, accounting for about 82.12% of all cancer new cases. Lung cancer, stomach cancer, liver cancer, esophageal cancer, colorectal cancer, female breast cancer, pancreatic cancer, brain tumor, leukemia and lymphoma were the leading causes of cancer death, accounting for about 89.01% of all cancer deaths. The cancer spectrum showed difference between urban and rural, males and females both in incidence and mortality rates.Conclusions: Cancer surveillance information in Shandong province is making great progress with the increasing number of cancer registries, population coverage and the improving data quality. Cancer registration plays a fundamental role in cancer control by providing basic information on population-based cancer incidence, mortality, survival and time trend. The disease burden of cancer is serious in Shandong province, and so cancer prevention and control in Shandong province should be enhanced including health education, health promotion, cancer screening and cancer care services. | Zhentao Fu Zilong Lu Yingmei Li jiyu Zhang Gaohui Zhang Xianxian Chen Jie Chu Jie Ren Haiyan Liu Xiaolei Guo | 2016 | Chinese Journal of Cancer Research2016，28，3： | 17 |
| 4 | Excessive UBE3A dosage impairs retinoic acid signaling and synaptic plasticity in autism spectrum disorders显示文摘孤独性光谱混乱(ASD ) 是有异构的病原学的许多人的神经病学的混乱。E3 ubiquitin (Ub ) 的活动过度 ligase UBE3A,不完全地源自 15q11-q13 拷贝数字变化,为世界范围的 ASD 盒子的 1%-3% 的报道,而是内在的机制遗体描绘了。这里,我们报导 ALDH1A2 的功能, retinoic 酸(RA ) 的限制率的酶合成,被 UBE3A 否定地以一种 ubiquitylation 依赖的方式调整。过多的 UBE3A 剂量被发现损害调停 RA 的 neuronal homeostatic synaptic 粘性。象 ASD 一样症状被 overexpressing UBE3A 在前额的外皮或由一个 ALDH1A 对手的管理在老鼠概括,而 RA 补充显著地减轻了过多的 UBE3A 导致剂量的象 ASD 一样显型。由识别在 ASD 作为内在的机制发信号的减少的 RA,显型连接了到 UBE3A 活动过度,我们的调查结果介绍 ASD 病原学的新远景并且对这逐渐地流行的疾病便于治疗学的开发的一个模式。 | Xingxing Xu Chuanyin Li Xiaobo Gao Kun Xia Hui Guo Yali Li ZijianHao Lei Zhang Daming Gao Chenfan Xu Huatai Xu Zhi-Qi Xiong Zilong Qiu Ling Mei Xiaoduo Xie Kangcheng Ruan Ronggui Hu | 2018 | Cell Research2018，28，1： | 13 |
| 5 | Persistent hepatitis C virus infections and hepatopathological manifestations in immune-competent humanized mice显示文摘 | Jizheng Chen Yang Zhao Chao Zhang Hairong Chen Jin Feng Xiumei Chi Yu Pan Jun Du Min Guo Huang Cao Honghe Chen Zilong Wang Rongjuan Pei Qian Wang Lei Pan Junqi Niu Xinwen Chen Hong Tang | 2014 | Cell Research2014，24，9： | 5 |
| 6 | Evaluation of the inhibition behavior of carbon dots on carbon steel in HCl and NaCl solutions显示文摘An eco-friendly and effective corrosion inhibitor(N-CDs)was acquired by hydrothermal method in methacrylic acid and ethyl(methyl)amine precursors.Afterwards,the weight loss and electrochemistry measurement were chosen to appraise the corrosion inhibition behavior of as-prepared N-CDs for Q235 steel in Cl-contained solutions.The change rules of EIS and Tafel data displayed that the as-prepared N-CDs revealed a high-efficiency protection for steel in all test environments.Meanwhile,the inhibition efficiency of steel reached up to 93.93%(1 M HCl)and 88.96%(3.5 wt%Na Cl)at 200 mg/L of N-CDs.Furthermore,the N-CDs could form the adsorption film on steel surface to avoid the strong attack of Cl-.By analysis,the adsorption mechanism of as-prepared N-CDs on steel surface was physicochemical interaction,which strictly complied with the Langmuir adsorption model in both solutions. | Yuwei Ye Zilong Jiang Yangjun Zou Hao Chen Shengda Guo Qiumin Yang Liyong Chen | 2020 | Journal of Materials Science & Technology2020，36，8： | 3 |
| 7 | Augmented renal clearance in Chinese intensive care unit patients after traumatic brain injury: a cross-sectional study显示文摘To the Editor:Augmented renal clearance(ARC)refers to an enhanced elimination of circulating solutes,including drugs,by the kidneys at a rate statistically higher than normal.On the first day of intensive care unit(ICU)admission,ARC occurrence may predict continued creatinine clearance(CrCl)elevation for 1 day to several weeks.[1]ARC has a substantial adverse effect on renally cleared antibiotics'pharmacokinetics/pharmacodynamics.Treatment failure or worse outcomes are more frequent in ARC patients.Thus,a'one size fits all'approach to drug dosing in ARC patients is inappropriate;dosing requires adjustment for some variables. | Zilong Dang Hong Guo Bin Li Maohua Zhen Jian Liu Yuhui Wei Hongyan Qin Zhimin Dou Lei Zhang Lei Zhu Yongqiang Cao Fengjiao Li Xinan Wu | 2022 | Chinese Medical Journal2022，，6： | 3 |
| 8 | Structure and antioxidant activity study of sulfated acetamido-polysaccharide from Radix Hedysari显示文摘 | Zilong Dang Demei Feng Xiaohua Liu Tao Yang Long Guo Jin Liang Jiandi Liang Fangdi Hu Fang Cui Shilan Feng | 2013 | Fitoterapia2013，，： | 2 |
| 9 | The effects of phenolic acid on nitrogen metabolism in Populus 3 euramericana ‘Neva’显示文摘The declines in soil fertility and productivity in continuously cropped poplar plantations are related to phenolic acid accumulation in the soil.Nitrogen is a vital life element for poplar and whether the accumulation of phenolic acid could influence nitrogen metabolism in poplar and thereby hinder continuous cropping is not clear.In this study, poplar cuttings of Populus × euramericana‘Neva’ were potted in vermiculite, and phenolic acids at three concentrations(0 X, 0.5 X and 1.0 X) were added according to the actual content(1.0 X) in the soil of a second-generation poplar plantation.Each treatment had eight replicates.We measured gas exchange parameters and the activities of key enzymes related to nitrogen metabolism in the leaves.Leaf photosynthetic parameters varied with the concentration of phenolic acids.The net photosynthetic rate(P_N) significantly decreased with increasing phenolic acid concentration, and non-stomatal factors might have been the primary limitation for P_N.The activities of nitrate reductase(NR), glutamine synthetase(GS) and glutamate synthase(GOGAT), as well as the contents of nitrate nitrogen, ammonium nitrogen, and total nitrogen in the leaves decreased with increasing phenolic acid concentration.This was significantly and positively related to P_N(P<0.05).The low concentration of phenolic acids mainly affected the transformation process of NO_3^- to NO_2^-, while the high concentration of phenolic acids affected both processes, where NO_3^- was transferred to NO_2^- and NH_4^+ was transferred to glutamine(Gln).Overall, phenolic acid had significant inhibitory effects on the photosynthetic productivity of Populus × euramericana‘Neva’.This was probably due to its influence on the activities of nitrogen assimilation enzymes, which reduced the amount of amino acids that were translated into protein and enzymes.Improving the absorption and utilization of nitrogen by plants could help to overcome the problems caused by continuous cropping. | Hui Li Huicheng Xie Zilong Du Xianshuang Xing Jie Zhao Jing Guo Xia Liu Shuyong Zhang | 2018 | Journal of Forestry Research2018，29，4： | 2 |
| 10 | A recommended rate for application of Chaetomium globosum ND35 fungus fertilizer on poplar plantations in China显示文摘Previous studies showed that Chaetomium globosum ND35 fungus fertilizer can improve the microbial community structure and enzyme activities of replanted soil.However, it remains unclear whether can improve the physiological and ecological characteristics of plants under successive rotation.In this study, we investigated the photosynthetic, physiological, and biochemical indexes including photosynthetic parameters, chlorophyll fluorescence, and chlorophyll content of 1-year-old poplar seedlings under seven different doses(range from 0 to1.67 g kg^(-1)) of C.globosum ND35 fungus fertilizer to study the effects of fungus fertilizer on photosynthesis of Poplar.Our results showed that:(1) With increasing application of fungus fertilizer in replanted soil, chlorophyll content of poplar leaves(Chl) increased, while physiological indexes such as electron transport rate(ETR),net photosynthetic rate(P_n), quantum efficiency(U),nitrate reductase(NR) activity and root vigor initially increased and then declined.Meanwhile, heat dissipation that depended on the xanthophyll cycle declined and nonphotochemical quenching(NPQ) initially increased and then decreased.When the dose of C.globosum ND35 fungus fertilizer was 0.67 g kg^(-1)(T3) and 1.00 g kg^(-1)(T4), excess light energy of photosynthetic apparatus was reduced, and photosynthetic apparatus distributed more light energy to the direction of photochemical reactions,which improved the efficiency of energy use.Plant height and biomass of leaves, stems, and roots were maximum at T3.We conclude that applying appropriate amounts of C.globosum ND35 fungus fertilizer can improve root physiological activity and capacity for use of light by poplar leaves.This can improve the operating states of the photosynthetic apparatus and lead to increased photosynthetic efficiency of poplar leaves and accumulation of dry matter.This suggests a strategy to alleviate the successive rotation obstacle of soil nutrient depletion. | Xuanxuan Xia Kexiang Gao Xianshuang Xing Rui Yang Shuyong Zhang Zilong Du Jing Guo Xia Liu | 2018 | Journal of Forestry Research2018，29，4： | 2 |
| 11 | Contrasting room-temperature hydrogen sensing capabilities of Pt-SnO2 and Pt-TiO2 composite nanoceramics显示文摘察觉到行为的形成对照的房间温度氢为 Pt-TiO 2 和 Pt-SnO 2 被揭示了合成 nanoceramics。在 Pt-TiO 2 nanoceramics 的情况中,超离频当在周围的空气的氧 / 氢集中比率到达批评价值时,氢敏感突然地被失去。在 Pt-SnO 2 nanoceramics 的情况中,然而,如此的现象不发生,并且察觉到能力的非凡的房间温度氢在空中面对氧被观察。我们的联合了试验性、理论的调查为系统建立统一机制,它在表面和 SnO 2 和 TiO 2 的空隙的格子地点上根植于氢化学吸着;在 SnO 2 和 TiO 2 上的使用化学方法吸附的氢的稳定性的差别为察觉到能力的形成对照的氢被认为负责。中央调查结果在在改变混合气体的集中在房间温度充实我们和各种各样的金属氧化物半导体(苔藓) 的氢相互作用的显微镜的理解是有用的,并且他们能在基于体积苔藓开发可靠房间温度氢传感器是有帮助的。 | Yao Xiong Wanping Chen Yesheng Li Ping Cui Shishang Guo Wei Chen Zilong Tang Zijie Yan Zhenyu Zhang | 2016 | Nano Research2016，9，11： | 1 |
| 12 | Combining high-throughput phenotyping and genome-wide association studies to reveal natural genetic variation in rice显示文摘 | Yang Wengneng Guo Zilong Huang Chenglong | 2014 | Nature Communications2014，11，5： | 1 |
| 13 | A novel immune evolutionary algorithm incoporating chaos optimization显示文摘 | Guo Zilong Wang Sun'an Zhuang Jian | 2006 | Pattern Recognition Letters2006，27，： | 1 |
| 14 | Natural Variation in the Sequence of SNAC1 and Its Expression Level Polymorphism in Rice Germplasms under Drought Stress显示文摘Water is a major limiting factor for food production and many countries fail to produce sufficient food for their population due to severe water scarcity(Jury and Vaux,2005).Rice is the main staple food worldwide.More than 50%of rice in the world is rain-fed and drought causes severe reduction in rice grain yield in rain-fed environments(Venuprasad et al.,2007;Zhang.2007;Sandhu et al.,2014).Therefore,enhancing drought resistance(DR)of rice is important for food security.However,DR is a complex trait,which is controlled by a large number of loci with small effect and is also affected by different genetic background,genotype-by-environment interaction and other stresses such as heat(Hu and Xiong, | Khamdok Songyikhangsuthor Zilong Guo Nili Wang Xiaoyi Zhu Weibo Xie Tongmin Mou Lizhong Xiong | 2014 | Journal of Genetics and Genomics2014，41，11： | 1 |
| 15 | A novel immune evolutionary algorithm incorporating chaos optimization 显示文摘 | Guo Zilong Wang Sun' an Zhuang Jian | 2006 | Pattern Recognition Letters2006，27，1： | 1 |
| 16 | Single-dose AAV-based vaccine induces a high level of neutralizing antibodies against SARS-CoV-2 in rhesus macaques显示文摘Dear Editor,Coronavirus disease 2019(COVID-19)is a highly infectious respiratory disease that continues to pose a serious global public health emergency.The disease shows a high infection rate,long incubation period,and rapidly emerging variants,which have led to its rapid spread worldwide(Krammer 2020).Many vaccines have been developed for the control of severe acute respiratory syndrome coronavirus 2(SARS-CoV-2),the virus responsible for COVID-19,including vaccines based on messenger RNA(mRNA)(Polack et al.2020),viral vectors(Zhu et al.2020),recombinant proteins(Yang et al.2020),and inactivated SARS-CoV-2(Zhang et al.2021). | Dali Tong Mei Zhang Yunru Yang Han Xia Haiyang Tong Huajun Zhang Weihong Zeng Muziying Liu Yan Wu Huan Ma Xue Hu Weiyong Liu Yuan Cai Yanfeng Yao Yichuan Yao Kunpeng Liu Shifang Shan Yajuan Li Ge Gao Weiwei Guo Yun Peng Shaohong Chen Juhong Rao Jiaxuan Zhao Juan Min Qingjun Zhu Yanmin Zheng Lianxin Liu Chao Shan Kai Zhong Zilong Qiu Tengchuan Jin Sandra Chiu Zhiming Yuan Tian Xue | 2023 | Protein & Cell2023，14，1： | 0 |
| 17 | Was Wuhan the early epicenter of the COVID-19 pandemic?——a critique显示文摘Recently, Worobey et al.(2022) published a report entitled ‘The Huanan Seafood Wholesale Market in Wuhan was the early epicenter of the COVID-19 pandemic' that succinctly summarizes their study [1]. A pre-print version of this study had earlier elicited a series of highprofile media coverages [2,3]. All these reports deliver a social-political message that the Huanan market is the epicenter of COVID-19. | Yanan Cao Lingling Chen Hua Chen Yupeng Cun Xiaofeng Dai Hongli Du Feng Gao Fengbiao Guo Yalong Guo Pei Hao Shunmin He Shunping He XiongLei He Zheng Hu Boon-Peng Hoh Xin Jin Qian Jiang Qinghua Jiang Asifullah Khan Hong-Zhi Kong Jinchen Li Shuai Cheng Li Ying Li Qiang Lin Jianquan Liu Qi Liu Jian Lu Xuemei Lu Shujin Luo Qinghua Nie Zilong Qiu Tieliu Shi Xiaofeng Song Jianzhong Su Sheng-ce Tao Chaolong Wang Chuan-Chao Wang Guo-Dong Wang Jiguang Wang Qi Wu Shaoyuan Wu Shuhua Xu Yu Xue Wenjun Yang Zhaohui Yang Kai Ye Yuan-Nong Ye Li Yu Fangqing Zhao Yiqiang Zhao Weiwei Zhai Dandan Zhang Liye Zhang Houfeng Zheng Qi Zhou Tianqi Zhu Ya-ping Zhang | 2023 | National Science Review2023，10，4： | 0 |
| 18 | Dynamic analysis and regulation of the flexible pipe conveying fluid with a hard-magnetic soft segment显示文摘The recently developed hard-magnetic soft(HMS)materials can play a significant role in the actuation and control of medical devices,soft robots,flexible electronics,etc.To regulate the mechanical behaviors of the cantilevered pipe conveying fluid,the present work introduces a segment made of the HMS material located somewhere along the pipe length.Based on the absolute node coordinate formulation(ANCF),the governing equations of the pipe conveying fluid with an HMS segment are derived by the generalized Lagrange equation.By solving the derived equations with numerical methods,the static deformation,linear vibration characteristic,and nonlinear dynamic response of the pipe are analyzed.The result of the static deformation of the pipe shows that when the HMS segment is located in the middle of the pipe,the downstream portion of the pipe centerline will keep a straight shape,providing that the pipe is stable with a relatively low flow velocity.Therefore,it is possible to precisely regulate the ejection direction of the fluid flow by changing the magnetic and fluid parameters.It is also found that the intensity and direction of the external magnetic field greatly affect the stability and dynamic response of the pipe with an HMS segment.In most cases,the magnetic actuation increases the critical flow velocity for the flutter instability of the pipe system and suppresses the vibration amplitude of the pipe. | Zilong GUO Qiao NI Wei CHEN Huliang DAI Lin WANG | 2022 | Applied Mathematics and Mechanics(English Edition)2022，43，9： | 0 |
| 19 | Genome-wide association study revealed genetic variations of ABA sensitivity controlled by multiple stress-related genes in rice显示文摘Abscisic acid(ABA)is a critical phytohormone that regulates multiple physiological processes including plant growth and stress tolerance.The core ABA signaling pathway has been well established,but genetic variations mediating ABA responses remain largely unknown.In this study,we performed genome-wide association study(GWAS)to identify loci and genes associated with ABA sensitivity(reflected by seed germination inhibition by ABA)in a panel of 425 rice accessions.The seed germination assay revealed that Aus and indica rice had stronger ABA sensitivity than japonica rice.A total of 48 non-redundant association loci were detected in the indica subpopulation and whole population,and 386 genes in these loci were responsive to ABA or abiotic stresses.Eight association loci were overlapped with previously reported loci for yield under drought stress or for droughtindicative image traits.Haplotype analyses of important candidate genes such as OsSAPK6,a key component in the ABA signaling core,were performed to identify key SNPs/InDels that may affect gene functions through promoter activity regulation,amino acid variation,or gene splicing.These results provide insights into the genetic basis of ABA sensitivity related to stress responses. | Lei Peng Tingting Xie Zilong Guo Xiaokai Li Yu Chang Haifu Tu Shengchang Wang Nai Wu Yilong Yao Lizhong Xiong | 2021 | Stress Biology2021，1，1： | 0 |
| 20 | Self-assembled donor-acceptor hole contacts for inverted perovskite solar cells with an efficiency approaching 22%: The impact of anchoring groups显示文摘Self-assembled molecules(SAMs) have shown great potential in replacing bulk charge selective contact layers in high-performance perovskite solar cells(PSCs) due to their low material consumption and simple processing. Herein, we design and synthesize a series of donor-acceptor(D-A) type SAMs(MPA-BTCA, MPA-BT-BA, and MPA-BT-RA, where MPA is 4-methoxy-N-(4-methoxyphenyl)-N-phenylaniline;BT is benzo[c][1,2,5]-thiadiazole;CA is 2-cyanoacrylic acid, BA is benzoic acid, RA is rhodanine-3-propionic acid) with distinct anchoring groups, which show dramatically different properties. MPA-BTCA with CA anchoring groups exhibited stronger dipole moments and formed a homogeneous monolayer on the indium tin oxide(ITO) surface by adopting an upstanding self-assembling mode. However, the MPA-BT-RA molecules tend to aggregate severely in solid state due to the sp~3 hybridization of the carbon atom on the RA group, which is not favorable for achieving a long-range ordered self-assembled layer.Consequently, benefiting from high dipole moment, as well as dense and uniform self-assembled film,the device based on MPA-BT-CA yielded a remarkable power conversion efficiency(PCE) of 21.81%.Encouragingly, an impressive PCE approaching 20% can still be obtained for the MPA-BT-CA-based PSCs as the device area is increased to 0.80 cm^(2). Our work sheds light on the design principles for developing hole selecting SAMs, which will pave a way for realizing highly efficient, flexible, and large-area PSCs. | Qiaogan Liao Yang Wang Zilong Zhang Kun Yang Yongqiang Shi Kui Feng Bolin Li Jiachen Huang Peng Gao Xugang Guo | 2022 | Journal of Energy Chemistry2022，31，5： | 0 |
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