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1Stretching and imaging studies of single DNA molecules显示文摘DNA molecules were stretched on silanized mica surface with the molecular combing technique, and detected with fluorescence microscopy and atomic force microscopy. Meantime, DNA molecules were stretched with a modified dynamic molecular combing technique and studied with atomic force microscopy. The results indicate that, compared with the dynamic molecular combing technique, the modified dynamic molecular combing technique has advantages of less-sample demand and less contamination to sample; as compared with the molecular combing technique, it has better aligning effect and reproducibility. Combination of this kind of DNA molecular manipulating technique with the single DNA molecule detecting technique by atomic force microscopy and fluorescence microscopy will play an important role in the basic research of molecular dynamics and the application of gene research.ZHANG Yi CHEN Shengfu OUYANG Zhenqian HU Jun XIONG Qihua LI Bin HUANG Yibo LI Minqian JIN Chengzhi 2000Chinese Science Bulletin2000,45,15:13
2Preparation of modified Ce-SAPO-34 catalysts and their catalytic performances of methanol to olefins显示文摘The modified Ce-SAPO-34 catalysts were prepared with three methods, i.e., the liquid ion exchange with air calcination, impregnation with air calcination and impregnation with steam calcination methods. The catalytic performances of the catalysts for methanol to olefins were investigated. The properties of the catalysts were characterized using XRD, BET, XRF, FT-IR and NH3-TPD. The results indicated that compared to the SAPO-34 catalyst the catalyst prepared with the impregnation and air calcination prolonged the lifetime by 40 min and improved the selectivity to ethylene by 5% (mol) and the catalyst prepared with the impregnation and steam calcination showed the best modification effect, prolonging the lifetime by 70 min and improving the ethylene selectivity by 10% (mol). The catalyst prepared with the liquid ion exchange showed similar behaviour as the SAPO-34 catalyst. It was verified that the porous structure and surface acidity of these catalysts determined their catalytic behaviors.Shuxun Tian Shengfu Ji Dandan Lü Bingyang Bai Qi Sun 2013Journal of Energy Chemistry2013,22,4:10
3Neural substrates of data-driven scientific discovery:An fMRI study during performance of number series completion task显示文摘Although much has been known about how humans psychologically perform data-driven scientific discovery,less has been known about its brain mechanism.The number series completion is a typical data-driven scientific discovery task,and has been demonstrated to possess the priming effect,which is attributed to the regularity identification and its subsequent extrapolation.In order to reduce the heterogeneities and make the experimental task proper for a brain imaging study,the number magnitude and arithmetic operation involved in number series completion tasks are further restricted.Behavioral performance in Experiment 1 shows the reliable priming effect for targets as expected.Then,a factorial design (the priming effect:prime vs.target;the period length:simple vs.complex) of event-related functional magnetic resonance imaging (fMRI) is used in Experiment 2 to examine the neural basis of data-driven scientific discovery.The fMRI results reveal a double dissociation of the left DLPFC (dorsolateral prefrontal cortex) and the left APFC (anterior prefrontal cortex) between the simple (period length=1) and the complex (period length=2) number series completion task.The priming effect in the left DLPFC is more significant for the simple task than for the complex task,while the priming effect in the left APFC is more significant for the complex task than for the simple task.The reliable double dissociation may suggest the different roles of the left DLPFC and left APFC in data-driven scientific discovery.The left DLPFC (BA 46) may play a crucial role in rule identification,while the left APFC (BA 10) may be related to mental set maintenance needed during rule identification and extrapolation.ZHONG Ning LIANG PeiPeng QIN YuLin LU ShengFu YANG YanHui LI KunCheng 2011Science China(Life Sciences)2011,54,5:8
4Effect of Ni Loading and Ce_(x)Zr_(1-x)O_(2) Promoter on Ni-Based SBA-15 Catalysts for Steam Reforming of Methane显示文摘有象 10wt%Ni/10wt%CexZr1_x:O2/SBA-15 一样从 5wt%到 20wt% 的镍内容的一系列 Ni/SBA-15 催化剂(x=0, 0.5, 1 ) 被准备。催化剂的结构用 XR.D, TPR, TEM 和赌注技术被描绘。为甲烷改过的蒸气的催化剂的催化活在连续流动被评估微反应堆。结果显示了那 Ni/SBA-15 和 Ni/CexZr1_x; O2/SBA-15 催化剂在气压有好催化活。10wt%Ni/SBA-15 催化剂在 800 点展出了优秀稳定性 ?? 在 740 h 的溪流上的时间的 6 号元素碳的化学符号。在反应以后,碳沉积没在催化剂的表面上被形成。在那里存在一常规六角形我在 Ni/SBA-15 和 Ni/CexZr1_x 的酣睡的结构; O2/SBA-15 催化剂。镍种类和 CexZr1_x; O2 部件都在 SBA-15 中央毛孔被限制。CexZr1_x; O2 能在 Ni/CexZr1_x 支持镍种类的分散; O2/SBA-15 催化剂。给词调音:基于 Ni 的催化剂;SBA-15;甲烷;冒热气改过;Huijun Wan Xiujin Li Shengfu Ji Bingyao Huang Kai Wang Chengyue Li 2007Journal of Natural Gas Chemistry2007,16,2:6
5Preparation of phosphorus-modified PITQ-13 catalysts and their performance in 1-butene catalytic cracking显示文摘A series of phosphorus-modified PITQ-13 catalysts was prepared by wet impregnation of NH4H2PO4solution into an HITQ-13 parent. The catalysts were characterized using XRD, N2adsorption, MAS NMR and NH3-TPD. Their catalytic performance in 1-butene catalytic cracking was evaluated in a fixed fluidized bed reactor. The results showed that the crystallinity, surface area and pore volume of P-modified PITQ-13catalysts decreased with the increasing amounts of P. The number of weak acid sites increased, whereas that of strong acidity decreased. The selectivity to propylene in 1-butene cracking reactions increased because of the decrease in strong acidity. The yield of propylene achieved41.6% over PITQ-13-2 catalyst with a P content of 1.0 wt%, which was 5.1% greater than that achieved over HITQ-13 catalyst.Penghui Zeng Yun Liang Shengfu Ji Baojian Shen Honghai Liu Baojie Wang Hongjuan Zhao Mingfu Li 2014Journal of Energy Chemistry2014,23,2:6
6Comparative study of fluidized-bed and fixed-bed reactor for syngas methanation over Ni-W/TiO_2-SiO_2 catalyst显示文摘In this work,syngas methanation over Ni-W/TiO2-SiO2catalyst was studied in a fluidized-bed reactor(FBR)and its performance was compared with a fixed-bed reactor(FIXBR).The effects of main operating variables including feedstock gases space velocity,coke content,bed temperature and sulfur-tolerant stability of 100 h life were investigated.The structure of the catalysts was characterized by XRD,N2adsorptiondesorption and TEM.It is found that under same space velocity from 5000 h 1to 25000 h 1FBR gave a higher CH4yield,lower coke content,and lower bed temperature than those obtained in FIXBR.Ni-W/TiO2-SiO2catalyst possessed excellent sulfur-tolerant stability on the feedstock gases less than 500 ppm H2S in FBR.The carbon deposits formed on the spent catalyst were in the form of carbon fibers in FBR,while in the form of dense accumulation distribution appearance in FIXBR.Bo Liu Shengfu Ji 2013Journal of Energy Chemistry2013,22,5:6
7Magnetically recyclable Pd/γ-AlOOH@Fe_3O_4 catalysts and their catalytic performance for the Heck coupling reaction显示文摘Novel magnetically recyclable Pd/γ-AlOOH@Fe3O4 catalysts were prepared using γ-AlOOH@Fe3O4 as a magnetic supporter and nano-Pd particles as the active catalytic component.The structure of the catalysts was characterized by X-ray diffraction(XRD),transmission electron microscopy(TEM),N2 adsorption-desorption,and a vibration sample magnetometer(VSM).The catalytic activity and recyclability for the Heck coupling reaction were investigated.Results showed that the magnetic γ-AlOOH@Fe3O4 possessed a core-shell structure,as well as that the nano-Pd particles were 6–8 nm and had been well dispersed in the γ-AlOOH shell.In the Heck coupling reactions,the magnetic Pd/γ-AlOOH@Fe3O4 catalysts exhibited good catalytic activity and recyclability.For the(0.021 mol%)Pd/γ-AlOOH@Fe3O4 catalyst,the bromobenzene conversion and product yield reached about 100%and 96.3%,respectively,under a 120°C reaction temperature and 12 h reaction time.After being recycled 8 times,the conversion of bromobenzene and the recovery of the catalyst were about 90%and 93%,respectively.The nano-Pd particles were kept well dispersed in the used Pd/γ-AlOOH@Fe3O4 catalyst.YANG Hao JI ShengFu LIU XueFei ZHANG DanNi SHI Da 2014Science China Chemistry2014,57,6:5
8Effect of Cu promoter on Ni-based SBA-15 catalysts for partial oxidation of methane to syngas显示文摘A series of Ni/SBA-15 catalysts with 5wt% to 15wt% Ni content as well as a series of 12.5%Ni/Cu/SBA-15 catalysts with 1% to 10% copper content were prepared by the impregnation method. The catalytic performance for partial oxidation of methane was investigated in a continuous flow microreactor under atmospheric pressure. The textural and chemical properties of the catalysts were characterized by XRD,TEM,BET and H 2-TPR techniques. The results indicated that the catalysts modified with Cu promoter showed better performance than those without modification. For the 12.5%Ni/2.5%/Cu/SBA-15 catalyst,at 850 C the conversion of CH 4 reached 97.9% and the selectivity of CO and H 2 reached 98.0% and 96.0%,respectively. In XRD patterns of the Ni/Cu/SBA-15 catalyst with 7.5 to 10% Cu contents there were CuO characteristic peaks beside NiO characteristic peaks. The mesoporous structure of SBA-15 was retained in all of the catalysts. TPR analysis of the catalysts revealed that a strong interaction between Ni,Cu promoter and SBA-15 support may be existed. This interaction enhanced significantly the redox properties of the catalysts resulting in the higher catalytic activity.Fabien Habimana Xiujin Li Shengfu Ji Bao Lang Daoan Sun Chengyue Li 2009Journal of Natural Gas Chemistry2009,18,4:4
9Variations in silicate concentration affecting photosynthetic carbon fixation by spring phytoplankton assemblages in surface water of the Strait of Malacca显示文摘The Strait of Malacca (SoM), the world's busiest sea-route, is increasingly polluted as the rapid development of world trades, affecting phytoplankton primary productivity therein. The variations of surface phytoplankton biomass, size-structure and carbon fixation were investigated across the SoM during the spring period (May 4 to 9, 2011). Chlorophyll a concentration increased from 0.12 μg/L at the northwest entrance of the SoM to a maximal 0.63 μg/L at narrowest section, and decreased to 0.10 μg/L at the southeast entrance. Photosynthetic carbon fixation by phytoplankton coincided well with Chl a biomass, and increased from 10.8 to 22.3 μg C/(L d), then decreased to 9.21 μg C/(L d); while the carbon fixation rate showed an inverse pattern to the changes of Chl a, and decreased from 87.1 to 35.5 μg C/(μg Chl a d) and increased thereafter to 95.3 μg C/(μg Chla·d). Picophytoplankton cells (<3 μm) contributed to more than 60% and 50% of the total Chl a and carbon fixation at both the entry waters; while the contributions of pico-cells decreased sharply to the minimum of 18.3% and 27.5% at the narrowest part of the SoM. In particular, our results showed that the silicate concentration positively regulated Chl a biomass and carbon fixation, reflecting that the higher silicate favoured the growth of phytoplankton and thus led to higher primary production in this strait.LI Gang LIN Qiang SHEN Pingping NI Guangyan SONG Xingyu WANG Shengfu FAN Yanzhi HUANG Liangmin TAN Yehui 2013Acta Oceanologica Sinica2013,32,4:4
10Dynamic Modeling and Experiment of a New Type of Parallel Servo Press Considering Gravity Counterbalance显示文摘The large capacity servo press is traditionally realized by means of redundant actuation,however there exist the over-constraint problem and interference among actuators,which increases the control difficulty and the product cost.A new type of press mechanism with parallel topology is presented to develop the mechanical servo press with high stamping capacity.The dynamic model considering gravity counterbalance is proposed based on the virtual work principle,and then the effect of counterbalance cylinder on the dynamic performance of the servo press is studied.It is found that the motor torque required to operate the press is a lot less than the others when the ratio of the counterbalance force to the gravity of ram is in the vicinity of 1.0.The stamping force of the real press prototype can reach up to 25 MN on the position of 13 mm away from the bottom dead center.The typical deep-drawing process with 1200 mm stroke at 8 strokes per minute is proposed by means of five order polynomial.On this process condition,the driving torques are calculated based on the above dynamic model and the torque measuring test is also carried out on the prototype.It is shown that the curve trend of calculation torque is consistent to the measured result and that the average error is less than 15%.The parallel mechanism is introduced into the development of large capacity servo press to avoid the over-constraint and interference of traditional redundant actuation,and its dynamic characteristics with gravity counterbalance are presented.HE Jun GAO Feng BAI Yongjun WU Shengfu 2013Chinese Journal of Mechanical Engineering2013,26,6:4
11Effect of MgO promoter on Ni-based SBA-15 catalysts for combined steam and carbon dioxide reforming of methane显示文摘A series of Ni/SBA-15 catalysts with Ni contents ranging from 5 wt% to 15 wt%, as well as another series of 10%Ni/MgO/SBA-15 catalysts, in which the range of the MgO content was from 1 wt% to 7 wt%, were prepared, and their catalytic performances for the reaction of combined steam and carbon dioxide reforming of methane were investigated in a continuous flow microreactor. The structures of the catalysts were characterized using the XRD, H2-TPR and CO2-TPD techniques. The results indicated that the CO selectivity for this reaction was very close to 100%, and the H2/CO ratio of the product gas could be controlled by changing the H2O/CO2 molar ratio of the feed gas. The simultaneous and plentiful existing of steam and CO2 had a significant influence on the catalytic performance of the 10%Ni/SBA-15 catalyst without modification. After reacting at 850 °C for 120 h over this catalyst, the CH4 conversion dropped from 98% to 85%, and the CO2 conversion decreased from 86% to 53%. However, the 10%Ni/3%MgO/SBA-15 catalyst exhibited a much better catalytic performance, and after reacting for 620 h, the CO2 conversion over this catalyst dropped from 92% to around 77%, while the CH4 conversion was not decreased. Oxidation of the Ni0 species as well as carbon deposition during the reaction were the main reasons for the deactivation of the catalyst without modification. On the other hand, modification by the MgO promoter improved the dispersion of the Ni0 species, and enhanced the CO2 adsorption affinity which in turn depressed the occurring of carbon deposition, and thus retarded the deactivation process.Bingyao Huang Xiujin Li Shengfu Ji Bao Lang Fabien Habimana Chengyue Li 2008Journal of Natural Gas Chemistry2008,17,3:3
12Particle/metal-based monolithic catalysts dual-bed reactor with beds-interspace supplementary oxygen:Construction and performance for oxidative coupling of methane显示文摘A novel particle/metal-based monolithic catalysts dual-bed reactor with beds-interspace supplementary oxygen is constructed comprising of the upper-layer 5wt%Na2WO4-2wt%Mn/SiO2 particle catalyst and the under-layer 3 wt%Ce-5 wt%Na2WO4-2 wt%Mn/SBA-15/Al2O3 /FeCrAl metal-based monolithic catalyst as well as a side tube in the interspaces of two layers for supplementing O2.The reaction performance of oxidative coupling of methane(OCM) in the dual-bed reactor system is evaluated.The effects of the reaction parameters such as feed CH 4 /O 2 ratio,reaction temperature and side tube feed O2 flowrate on the catalytic performance are investigated.The results indicate that the suggested mode of dual-bed reactor exhibits an excellent performance for OCM.CH4 conversion of 33.2%,C2H4 selectivity of 46.5% and C2 yield of 22.5% could be obtained,which have been increased by 6.4%,4.1% and 5.5%,respectively,as compared with 5 wt%Na2WO4-2 wt%Mn/SiO2 particle catalyst in a single-bed reactor and increased by 10.7%,31.9% and 17.7%,respectively,as compared with 3 wt%Ce-5 wt%Na2WO4-2 wt%Mn/SBA-15/Al2O3 /FeCrAl metal-based monolithic catalyst in a single-bed reactor.The effective promotion of OCM performance in the reactor would supply a valuable reference for the industrialization of OCM process.Wenhua Wang Zhao Zhang Shengfu Ji 2012Journal of Natural Gas Chemistry2012,21,4:3
13Synthesis of mesoporous γ-AlOOH@Fe_3O_4 magnetic nanomicrospheres显示文摘Mesoporous γ-AlOOH@Fe3O4 magnetic nanomicrospheres were synthesized using superparamagnetic Fe3O4 nanoparticles as the core and aluminum isopropoxide(AIP) as the aluminum source.The obtained magnetic nanomicrospheres were characterized by X-ray powder diffraction(XRD),transmission electron microscopy(TEM),scanning electron microscopy(SEM),N2 adsorption-desorption and vibrating sample magnetometry(VSM).The effects of preparation parameters such as hydrolysis time of AIP,concentration of AIP and coating layer number on microspheres were investigated.The results indicated that the mesoporous γ-AlOOH@Fe3O4 magnetic nanomicrospheres consisted of a mesoporous-AlOOH shell and a Fe3O4 magnetic core.The diameter of γ-AlOOH@Fe3O4 nanomicrospheres was about 200 nm,the thickness of mesoporous-AlOOH shell was about 5 nm and the average pore size was 3.8 nm.The thickness of the mesoporous-AlOOH shell could be controlled via layer-by-layer coating times.The formation mechanism of the mesoporous-AlOOH shell involved a 'chemisorption-hydrolysis' process.Yuanyuan Zheng Shengfu Ji Hongfei Liu Ming Li Hao Yang 2012Particuology2012,10,6:3
14Identification of the candidate genes associated with cellular rejection in pig-to-human xenotransplantation显示文摘To identify the genes associated with cellular rejection in pig-to-human xenotransplantation, the suppression subtractive hybridization (SSH) was used in screening the up-regulated genes from a co-culture of human peripheral blood mononuclear cells (PBMCs) and porcine vascular endothelial cell line PIEC. The up-regulated cDNAs were cloned into pGEM-T Easy vector and then sequenced. Nucleic acid homology searches were performed using the BLAST program. A subtracted cDNA library including about 300 clones with the expected up-regulated genes was obtained. Twenty-four of these clones were analyzed by sequencing and homology comparison was made. These clones represent the genes of human perforin (PRF1), proteasome, lymphocyte specific interferon regulatory factor/interferon regulatory factor 4 (LSIRF/IRF 4), muscleblind-like (MBNL) protein and a porcine expressed sequence tag (EST) which has 81% homology with human oxidative-stress responsive 1 (OSR 1). These genes might be the candidate genes which are associated with cellular rejection in pig-to-human xenotransplantation.HU Weimin, CHENG Jingqiu, LI Youping , LI Shengfu, LU Xiaofeng and WAN Lin(Laboratory of Transplant Engineering and Immunology, West China Hospital, Sichuan University, Chengdu 610041, China) 2002Progress in Natural Science:Materials International2002,12,9:3
15Hydrogen generation from methanolysis of sodium borohydride over Co/Al_2O_3 catalyst显示文摘Co/Al2O3 catalyst is prepared with an impregnation-chemical reduction method and used to catalyze the methanolysis of sodium borohydride (NaBH 4) for hydrogen generation.At solution temperature of 0 C,the methanolysis reaction can be effectively accelerated using Co/Al2O3 catalyst and provide a desirable hydrogen generation rate,which makes it suitable for applications under the circumstance of low environmental temperature.The byproduct of methanolysis reaction is analyzed by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR).The characterization results indicate that methanol can be easily recovered after methanolysis reaction by hydrolysis of the methanolysis byproduct,NaB(OCH 3) 4.The catalytic activity of Co/Al2O3 towards NaBH 4 methanolysis can be further improved by appropriate calcination treatment.The catalytic methanolysis kinetics and catalyst reusability are also studied over the Co/Al2O3 catalyst calcined at the optimized temperature.Dongyan Xu Lin Zhao Ping Dai Shengfu Ji 2012Journal of Natural Gas Chemistry2012,21,5:3
16Artificial intelligence assisted light control and computational imaging through scattering media显示文摘Coherent optical control within or through scattering media via wavefront shaping has seen broad applications since its invention around 2007.Wavefront shaping is aimed at overcoming the strong scattering,featured by random interference,namely speckle patterns.This randomness occurs due to the refractive index inhomogeneity in complex media like biological tissue or the modal dispersion in multimode fiber,yet this randomness is actually deterministic and potentially can be time reversal or precompensated.Various wavefront shaping approaches,such as optical phase conjugation,iterative optimization,and transmission matrix measurement,have been developed to generate tight and intense optical delivery or high-resolution image of an optical object behind or within a scattering medium.The performance of these modula-tions,however,is far from satisfaction.Most recently,artifcial intelligence has brought new inspirations to this field,providing exciting hopes to tackle the challenges by mapping the input and output optical patterns and building a neuron network that inherently links them.In this paper,we survey the developments to date on this topic and briefly discuss our views on how to harness machine learning(deep learning in particular)for further advancements in the field.Shengfu Cheng Huanhao Li Yunqi Luo Yuanjin Zheng Puxiang Lai 2019Journal of Innovative Optical Health Sciences2019,,4:2
17A method to refine the start-up scheme of compression and refrigeration systems in ethylene plants via dynamic simulation显示文摘Starting the cracking gas compressor and precooling the refrigeration system are keys to start-up of an ethylene plant and accounts for up to 50% of the total start-up time and plant flare emissions. Premature feeding of cracking furnaces can be avoided if the cracking gas compressor is started and the refrigeration system is precooled in advance using mixed gas as the start-up working medium(SWM). Start-up scenario with mixed gas as SWM could significantly reduce the emission loss and shorten the precooling time. Research shows that making appropriate start-up scheme is important not only to ensure operational safety and feasibility, but also to reduce energy consumption. In this paper, a method is proposed to select suitable start-up operational parameters of compression and refrigeration system with sufficient safe operating ranges and short precooling time. The complex interrelation among key parameters of start-up is analyzed. It is found that higher energy consumption, especially for super high-pressure steam(SS), can promote operational safety and shorten the precooling time during start-up.Based on steady-state and dynamic simulation, appropriate operating parameter ranges are determined with reasonable SS consumption. A real case study demonstrates that an appropriate start-up scheme will optimize the operation.Shengfu Zhang Yongchen Zhao Tong Qiu Guang Song Jinsong Zhao 2016Chinese Journal of Chemical Engineering2016,24,8:2
18Research on data diagnosis method of acoustic array sensor device based on spectrogram显示文摘Acoustic array sensor device for partial discharge detection is widely used in power equipment inspection with the advantages of non-contact and precise positioning compared with partial discharge detection methods such as ultrasonic method and pulse current method.However,due to the sensitivity of the acoustic array sensor and the influence of the equipment operation site interference,the acoustic array sensor device for partial discharge type diagnosis by phase resolved partial discharge(PRPD)map might occasionally presents incorrect results,thus affecting the power equipment operation and maintenance strategy.The acoustic array sensor detection device for power equipment developed in this paper applies the array design model of equal-area multi-arm spiral with machine learning fast fourier transform clean(FFT-CLEAN)sound source localization identification algorithm to avoid the interference factors in the noise acquisition system using a single microphone and conventional beam forming algorithm,improves the spatial resolution of the acoustic array sensor device,and proposes an acoustic array sensor device based on the acoustic spectrogram.The analysis and diagnosis method of discharge type of acoustic array sensor device can effectively reduce the system misjudgment caused by factors such as the resolution of the acoustic imaging device and the time domain pulse of the digital signal,and reduce the false alarm rate of the acoustic array sensor device.The proposed method is tested by selecting power cables as the object,and its effectiveness is proved by laboratory verification and field verification.Xing Lei Hang Ji Qiang Xu Ting Ye Shengfu Zhang Chengjun Huang 2022Global Energy Interconnection2022,5,4:2
19Numerical simulation of the temperature field of titania-bearing BF slag heated in a microwave oven显示文摘Considering the characteristic of selective heating of microwave and the treatment of titania-bearing BF slag, a mathematical model for the heating of a slag specimen is developed. The temperature distribution in the specimen is studied by numerical simulation. The temperature in the center of the cylindrical slag specimen is the highest and the temperature decreases when the radius increases rapidly. In this case, the temperature rising rate decreases with heating time rapidly, and it tends to zero when the heating time is up to 150 s.Liangying Wen Chenguang Bai Guibao Qiu Jian Zhang Shengfu Zhang Zhanjun Long 2008Journal of University of Science and Technology Beijing2008,15,4:2
20A quasi-3D Fano resonance cavity on optical fiber end-facet for high signal-to-noise ratio dip-and-read surface plasmon sensing显示文摘Surface plasmon devices mounted at the end-facets of optical fibers are appealing candidates for rapid and point-of-care sensing applications,by offering a special dip-and-read operation mode.At present,these devices’noise-equivalent limits-of-detection lag far behind the free-space counterparts,leaving them incapable of most biosensing applications.Here we report a quasi-3D Fano resonance cavity and its fabrication method to fundamentally improve the quality factor and coupling efficiency for fiber-coupled surface plasmon resonance.In this device,the Fano resonance combines the high coupling efficiency of a Fabry-Pérot etalon and the high quality factor resonance of a plasmonic crystal cavity.The quasi-3D device was fabricated on a planar substrate and transferred to a single-mode fiber end-facet,which requires a low-adhesion yet surface-plasmon-tunneling interface between the device and the planar substrate.Such an interface was realized with a nanocap-slit unit structure,of which the plasmonic crystal was consisted.A noise-equivalent limit of detection of~10-7 RIU was experimentally obtained,allowing bovine serum albumin physical adsorption to be distinguished at ng mL-1 level concentrations.Therefore,breaking through the long-standing signal-to-noise ratio bottleneck,this work makes fiber end-facet surface plasmon devices into one of high sensitivity label-free sensing technologies.At the same time,it provides an enabling top-down fabrication technology for making 3D plasmonic structures on fiber end-facets at the nanometer scale.Xiaqing Sun Zeyu Lei Hao Zhong Chenjia He Sihang Liu Qingfeng Meng Qingwei Liu Shengfu Chen Xiangyang Kong Tian Yang 2022Light(Advanced Manufacturing)2022,3,4:2
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