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| 1 | Fluorine-containing oxidizers for metal fuels in energetic formulations显示文摘Fluorine containing oxidizers, primarily polymers, are extensively used in pyrotechnic compositions.Fluorinated oxidizers are less explored for metalized propellants and explosives despite a potential advantage of substantial heat release combined with gaseous combustion products. This review summarizes different types of fluorinated oxidizers used in energetic formulations or of potential interest for such systems, including gases, polymers, and inorganic compounds. Types of energetic formulations employing metals and fluoropolymers are discussed in more detail, including methods used to prepare composites and resulting salient features of the obtained materials. Laboratory experiments characterizing such materials, in particular, electron microscopy and thermal analysis, are discussed, showing characteristic morphologies and reaction sequences observed in different metal-fluorinated oxidizer composites. Striking similarities are noted in reaction sequences for diverse compositions hinting at possible similarities in the respective reaction mechanisms. Experiments probing ignition and combustion of metal-fluorinated oxidizer composites in laboratory conditions are also reviewed, including impact, flash heating and shock ignition. Finally, some practical performance tests for energetic formulations are described following by a brief discussion of the reaction mechanisms expected to govern ignition and combustion in various metal-fluorinated oxidizer composites. The conclusions are combined with recommendation for future research in the area of reactive metal-fluorinated oxidizer composites. | Siva Kumar Valluri Mirko Schoenitz Edward Dreizin | 2019 | Defence Technology(防务技术)2019，15，1： | 17 |
| 2 | Calorimetric investigation of the aluminum-water reaction显示文摘 | NIE H SCHOENITZ M DREIZIN E L | 2012 | International Journal of Hydrogen Energy2012，37，11： | 1 |
| 3 | Fully dense nano- composite energetic powders prepared by arrested reactive milling显示文摘 | Schoenitz M Ward T S Dreizin E L | 2005 | Proceedings of the Combustion Institute2005，30，2： | 1 |
| 4 | Ig- nition of aluminum powders under different experimental conditions 显示文摘 | Mikhaylo A Trunov Mirko Schoenitz Edward L Dreizin | 2005 | Propellants Explosives Pyrotechnics2005，30，1： | 1 |
| 5 | Control of structural refinement and composition in Al-MoO3 nanocomposites prepared by arrested reactive milling显示文摘 | Umbrajkar S M Schoenitz M Dreizin E L | | 0，，5： | 1 |
| 6 | Aluminum-rich Al-MoO3 nanocomposite powders prepared by arrested reactive milling显示文摘 | Umbrajkar S M Seshadri S Schoenitz M | | 0，，2： | 1 |
| 7 | Aluminum metal reactivecomposites 显示文摘 | Aly Y Schoenitz M Dreizin E L | 2011 | Combustion Science and Technology2011，183，10： | 1 |
| 8 | Effect of polymorphic phase transformations in alumina layer on ignition of alumi- num particles 显示文摘 | Trunov M A Schoenitz M Dreizin E L | 2006 | Combustion Theory and Modeling2006，10，4： | 1 |
| 9 | Effect of poly- morphic phase transformations in A1203 film on oxida- tion kinetics of aluminum powders显示文摘 | Trunov M A Schoenitz M Zhu X | 2005 | Combustion and Flame2005，140，4： | 1 |
| 10 | Effect of poly- morphic phase transformations in alumina layer on ig- nition of aluminum particles显示文摘 | Trunov M A Schoenitz M Dreizin E L | 2006 | Combustion Theory' and Modeling2006，10，4： | 1 |
| 11 | Alttminum-rich AI-MoO3 nanocomposite powders prepared by arrested reactive milling显示文摘 | Swati M Umbrajkar Soumitri Seshadri Mirko Schoenitz | 2008 | Journal ofpropulsion and power2008，24，2： | 1 |
| 12 | Exothermic reactions in Al-CuO nanocomposites显示文摘 | Umbrajkar S M Schoenitz M Dreizin E L | 2006 | Thermo-chimica Acta2006，451，12： | 1 |
| 13 | Effect of polymorphic phase transformations in alumina layer on ignition of aluminum particles显示文摘 | Trunov M A Schoenitz M Dreizin E L | 2006 | Combustion Theory and Modeling2006，10，4： | 1 |
| 14 | Ignition of alumi- num powders under different experimental conditions 显示文摘 | Trunov M A Schoenitz M Dreizin E L | 2005 | Propellants Explosives Pyrotechnics2005，30，1： | 1 |
| 15 | Control of structural refinement and composition in Al-MoO3 nano- composites prepared by arrested reactive milling显示文摘 | Umbrajkar S M Schoenitz M Dreizin E L | 2006 | Propellants Explosives Pyrotechnics2006，31，5： | 1 |
| 16 | Kinetic analysis of thermite reactions in Al-MoO3 nanocomposites 显示文摘 | Schoenitz Mirko Umbrajkar Swati Dreizin Edward L | 2007 | Journal of Propulsion and Power2007，23，4： | 1 |
| 17 | Oxi- dation and Melting of Aluminum Nanopowders显示文摘 | Trunov M A Umbrajkar S M Schoenitz M | 2006 | Jour- nal of Physical Chemistry B2006，110，： | 1 |
| 18 | Reducing HIV transmission by seronegative blood显示文摘 | ZANGERLE R SCHOENITZER D FUCHS D | 2003 | Lancet2003，339，： | 1 |
| 19 | Ignition of aluminum powders under different experimental conditions 显示文摘 | TRUNOV M A SCHOENITZ M DREIZIN E L | 2005 | Propellants Explosives Pyrotechnies2005，30，1： | 1 |
| 20 | Exothermic reactions in Al-CuO nanocomposites显示文摘 | UMBRAJKAR S M SCHOENITZ M DREIZIN E L | 2006 | Thermochimica Acta2006，451，： | 1 |
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