|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | A review of electrolyte additives and impurities in vanadium redox flow batteries显示文摘As one of the most important components of the vanadium redox flow battery(VRFB), the electrolyte can impose a significant impact on cell properties, performance and capital cost. In particular, the electrolyte composition will influence energy density, operating temperature range and the practical applications of the VRFB. Various approaches to increase the energy density and operating temperature range have been proposed. The presence of electrolyte impurities, or the addition of a small amount of other chemical species into the vanadium solution can alter the stability of the electrolyte and influence cell performance, operating temperature range, energy density, electrochemical kinetics and cost effectiveness. This review provides a detailed overview of research on electrolyte additives including stabilizing agents, immobilizing agents, kinetic enhancers, as well as electrolyte impurities and chemical reductants that can be used for different purposes in the VRFBs. | Liuyue Cao Maria Skyllas-Kazacos Chris Menictas Jens Noack | 2018 | Journal of Energy Chemistry2018，27，5： | 7 |
| 2 | Thermal stability of concentrated Ⅴ(Ⅴ) electrolytes in the vanadium redox cell显示文摘 | SKYLLAS-KAZACOS M MENICTAS C KAZACOS M | 1996 | J Electrochem Soc1996，143，4： | 1 |
| 3 | The influence of electrochemical treatment on electrode reactions for vanadium redox-flow batteries显示文摘Through targeted and reproducible electrochemical treatment of glassy carbon electrodes,investigations have been carried out on the electrochemical behaviour of the oxidation of V^(2+),VO^(2+)and the reductions of VO_2^+,VO^(2+)and V^(3+)in order to pretreat electrodes specifically for use in vanadium redox flow batteries and,if possible,to treat them in situ.For this purpose,a glassy carbon electrode was treated potentiostatically for a period of 30 s at different potentials in the range of 500 mV–2000 mV vs.Hg/Hg_2SO_4in2 M H_2SO_4and then linear sweep voltammograms were performed in the different vanadium-containing solutions.With this method,it could be shown that all reactions are extremely surface sensitive and the reaction speeds changed by several decades.The reaction rates increased significantly in all reactions compared to polished electrodes and had an optimum treatment potential of approx.1600 mV vs.Hg/Hg_2SO_4,although the oxidation reaction of V^(2+)and the reduction reactions of V^(3+)and VO^(2+)had opposite tendencies to oxidation of VO^(2+)and the reduction of VO_2^+in the area of low treatment potentials.In the former,the kinetics increased and in the latter,they decreased.In addition,causes were investigated using confocal microscopy and XPS.No correlation was found to the roughness or size of the stretched surfaces,although these changed significantly as a result of the treatment.XPS measurements gave indications of a dependence on hydroxyl groups for the oxidation of VO^(2+)and the reduction of VO_2^+,while for the reactions of oxygen-free cations and the reduction of VO^(2+)weak indications of a dependence on carboxyl groups were obtained. | Jens Noack Nataliya RoznYatovskaya Jessica Kunzendorf Maria Skyllas-Kazacos Chris Menictas Jens Tubke | 2018 | Journal of Energy Chemistry2018，27，5： | 1 |
| 4 | Thermal stability of concentrated V( Ⅴ ) electrolytes in the vanadium redox cell显示文摘 | SKYLLAS KAZACOS M MENICTAS C KAZACOS M | 1996 | J Electrochem Soc1996，143，4： | 1 |
| 5 | Evaluation of an NI-LVO4 derived electrolyte for the vanadium-redox flow battery显示文摘 | MENICTAS C CHENG M SKYLLAS-KAZASCOS M | 1993 | Journal of Power Sources1993，45，： | 1 |
| 6 | Review of material research and development for vanadium redox flow battery applications显示文摘 | Aishwarya Parasuraman Tuti Mariana Lim Chris Menictas Maria Skyllas-Kazacos | 2013 | Electrochimica Acta2013，，： | 1 |
| 7 | Thermal stability of concentrated V(V) electrolytes in the vanadium redox cell 显示文摘 | SKYLLAS-KAZACOS M MENICTAS C KAZACOS M | 1996 | J ElectrochemSoc1996，143，4： | 1 |
| 8 | Thermal stability of concentrated V( V ) electrolytes in the vanadium redox cell显示文摘 | SKYLLAS-KAZACOS M MENICTAS C KAZACOS M | 1996 | J Electrochem Soc1996，143，4： | 1 |
| 9 | Thermal stability of concentrated V(V) electrolytes in the vanadium redox cell显示文摘 | SKYLLAS-KAZACOS M MENICTAS C SKYLLAS M | 1996 | J Electrochem Soc1996，143，4： | 1 |
| 10 | Novel bipolar electrodes for battery applications显示文摘 | MENICTAS C CHENG M SKYLLAS-KAZACOS M | 1993 | Journal of Ap- plied Electrochemistry1993，45，1： | 1 |
| 11 | Making sense of business process descriptions: An experimental comparison of graphical and textual notations显示文摘 | Avner Ottensooser Alan Fekete Hajo A. Reijers Jan Mendling Con Menictas | 2011 | The Journal of Systems & Software2011，，3： | 1 |
| 12 | Evaluation of an NH4V03- derived electrolyte for the vanadium- redox flow battery 显示文摘 | Menictas C Cheng M Skyllas - Kazacos M | 1993 | J Power Sources1993，45，： | 1 |
| 13 | Thermal stability of concentrated V(V) electrolytes in the vanadium redox cell显示文摘 | SKYLLAS-KAZACOS M MENICTAS C SKYLLAS M | 1996 | J Electrochem Soc1996，143，4： | 1 |
| 14 | Thermal stability of concentrated V(V) electrolytes in the vanadium redox cell显示文摘 | Skyllas-Kazacos M Menictas C | 1996 | J Electrochem Soc1996，143，： | 1 |
| 15 | Thermal stability of concentrated V (V) electrolytes in the vanadium redox cell显示文摘 | Skyllas - Kazacos M Menictas C Kazacos M | 1996 | J Electrochem Soc1996，143，： | 1 |
您所在的机构暂未开通此部分的功能，请联系管理员