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| 1 | 机械化学法制备的Al/Ce复合氧化物负载NiMo催化剂的加氢脱硫活性(英文)显示文摘将Al和/或Ce的硝酸盐与NH_4HCO_3球磨混合,采用机械化学法制备了Al_2O_3-CeO_2载体(其中Ce含量为1-10 wt%),再以杂多钼酸盐(NH_4)_4NiMo_6O_(24)为活性金属Ni和Mo的前驱体,通过浸渍法制备NiMo_6/Al_2O_3-CeO_2催化剂,并将其用于1-苯并噻吩(BT)的加氢脱硫(HDS)反应中.运用化学分析、X射线衍射、N_2吸附-脱附法、H_2程序升温还原、NH_3程序升温脱附和X射线光电子能谱对催化剂的物化性质进行了表征.结果表明,催化剂的酸性随着载体中Ce含量的增加而下降.Ce修饰的Al_2O_3载体表面的NiS/MoS原子比下降了2倍.NiMo_6/Al_2O_3催化剂表现出最高的HDS活性(以单位重量催化剂计),其酸性和表面MoO_xS_y物种的浓度(Mo^(5+)浓度)也最高;当催化剂中Ce含量逐渐增加到10 wt%以上时,其活性逐渐将为0.与浸渍法制得的参比催化剂相比,前驱体和催化剂组成相同的情况下,采用机械化学法制得的所有催化剂活性明显提高. | Květa Jirátová Alla Spojakina Luděk Kaluza Radostina Palcheva Jana Balabánová Georgi Tyuliev | 2016 | Chinese Journal of Catalysis2016，37，2： | 6 |
| 2 | 镍钼杂多酸制备NiMo/γ-Al_2O_3催化剂及硼、钴或镍改性氧化铝的影响(英文)显示文摘A hydrotreating NiMo/γ-Al2O3 catalyst(12 wt% Mo and 1.1 wt% Ni) was prepared by impregnation of the support with the Anderson-type heteropolyoxomolybdate(NH4)4Ni(OH)6Mo6O18.Before impregnation of the support,it was modified with an aqueous solution of H3BO3,Co(NO3)2,or Ni(NO3)2.The catalysts were investigated using N2 adsorption,O2 chemisorption,X-ray diffraction,UV-Vis spectroscopy,Fourier transform infrared spectroscopy,temperature-programmed reduction,temperature-programmed desorption,and X-ray photoelectron spectroscopy.The addition of Co,Ni,or B influenced the Al2O3 phase composition and gave increased catalytic activity for 1-benzothiophene hydrodesulfurization(HDS).X-ray photoelectron spectroscopy confirmed that the prior loading of Ni,Co or B increased the degree of sulfidation of the NiMo/γ-Al2O3 catalysts.The highest HDS activity was observed with the NiMo/γ-Al2O3 catalyst with prior loaded Ni. | Radostina PALCHEVA Luděk KALUZA Alla SPOJAKINA Květue JIRTOV Georgi TYULIEV | 2012 | 催化学报2012，33，6： | 6 |
| 3 | Different transcriptional activity and in vitro TNFα production in psoriasis patients carrying the TNFα 238A promoter polymorphism显示文摘 | Kaluza W Reuss E Crossman S | 2000 | J Invest Dematol2000，114，： | 2 |
| 4 | Targeting Tumor-Associated Macrophages with Anti-CSF-1R Antibody Reveals a Strategy for Cancer Therapy显示文摘 | Carola H. Ries Michael A. Cannarile Sabine Hoves J?rg Benz Katharina Wartha Valeria Runza Flora Rey-Giraud Leon P. Pradel Friedrich Feuerhake Irina Klaman Tobin Jones Ute Jucknischke Stefan Scheiblich Klaus Kaluza Ingo H. Gorr Antje Walz Keelara Abiraj Ph | 2014 | Cancer Cell2014，，： | 2 |
| 5 | Different transcriptional activity and in vitro TNF-α production in psoriasis patients carrying the TNF-α 238A promoter polymorphism 显示文摘 | Kaluza W Reuss E Grossmann S | 2000 | J Invest Dermatol2000，114，6： | 1 |
| 6 | High Activity ofHighly Loaded MoS2 Hydrodesulfurization Catalysts Supportedon Organised Mesoporous Alumina 显示文摘 | Kaluza L Zdrazil M Zilkova N | 2002 | Catal Commun2002，3，4： | 1 |
| 7 | Facilitated percutaneous coronary intervention in patients with acute myocardial infarction transferred from remote hospitals显示文摘 | Dudek D Zmudka K Kaluza GL | 2003 | Am J Cardiol2003，91，2： | 1 |
| 8 | Context-based ensemble method for man energy expenditure estimation显示文摘 | Hristijan Gjoreski Bostjan Kaluza Matjaz Gams Radoje Milic Mitja Lustrek | 2015 | Applied Soft Computing2015，13，： | 1 |
| 9 | Role of angiogenesis in patients with cerebral ischemic stroke显示文摘 | Krupinski J Kaluza J Kumar P | 1994 | Stroke1994，25，9： | 1 |
| 10 | Role of angiogenesis in patients with cerebral ischemic stroke显示文摘 | Krupinski J Kaluza J Kumar P | 1994 | Stroke1994，25，： | 1 |
| 11 | Role of angiogenesis inpatients with cerebral ischemic stroke显示文摘 | Krupinski J Kaluza J Kumar P | 1994 | Stroke* 1994>25(9):1 794-1 7981994，25，9： | 1 |
| 12 | Role of Angiogenesis in Patients With Cerebral Ischemic Stroke显示文摘 | Jerzy Krupinski Jozef Kaluza Pat Kumar Shant Kumar J. M. Wang | 1994 | Stroke1994，，9： | 1 |
| 13 | Role of angiogenesis in patients with cerebral ischemic stroke显示文摘 | Krupinski J Kaluza J Kumar P | 1994 | Stroke1994，25，： | 1 |
| 14 | Effect of support on the synergy in HDS of thiophene and of pyridine over sulfide catalysts promoted by RH 显示文摘 | VIT Z GULKOVA D KALUZA L | 2004 | Reaetion Kinetics and Catalysis Letters2004，83，2： | 1 |
| 15 | Zum unitaproblem der physik 显示文摘 | KALUZA T | 1921 | Sitz Preuss Akad Wiss Phys Math K1921，1，： | 1 |
| 16 | Enhancement of plaque for- marion and cell fusion of an enteropathogenic coronavirus bytrypsin treatment显示文摘 | Storz J R Rott G Kaluza | 1981 | Infect Immun1981，31，： | 1 |
| 17 | Prognostic value of blood ves- sel density in ischemic stroke显示文摘 | Krupinski J Kaluza J Kumar P | 1993 | Lancet1993，342，： | 1 |
| 18 | The complex network of global cargo ship movements显示文摘 | Kaluza P K-lzsch A Gastner M T Blasius B | 2010 | Journal of the Royal Society Interface2010，7，48： | 1 |
| 19 | 显示文摘 | Kaluza L | 2002 | Catalysis Communications2002，，3： | 1 |
| 20 | Role of angiogenesis in patients with cerebral ischemic stroke显示文摘 | Krupinski J Kaluza J Kumar P | 1994 | Stroke1994，25，： | 1 |
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