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1Ore-forming event and geodynamic setting of molybdenum deposit at Wenquan in Gansu Province,Western Qinling显示文摘The Wenquan molybdenum deposit is associated with a Triassic granite in this area.The Wenquan granite is enriched in LILE and LREE,poor in HFSE,and has significantly higher contents of alkali(K2O+Na2O) and Sr,Ba than those of the island arc volcanic rocks.These geochemical characteristics are similar to post-collisional granites in high K calc-alkaline series.Studies of major elements,trace elements,REEs and chronology of the Wenquan pluton show that,in the geodynamic transition stage of continent-continent convergence to extension,the partial melting of the enriched lithospheric mantle generated the basaltic magma and triggered the partial melting of the thickened lower crust which produceded the acidic magma,and the Wenquan pluton was formed by mixing of the two magmas.Molybdenite Re-Os isotopic dating gave Os model ages of 212.7±2.6 Ma to 215.1±2.6 Ma with a weighted mean of 214.1±1.1 Ma,and an Re-Os isochron age of 214.4±7.1 Ma.These ages are close to K-Ar ages(223 to 226 Ma) and a SHRIMP zircon U-Pb age(223±7 Ma) for the Wenquan granite within the error range,but relatively younger.This implies that the Mo mineralization occurred in a late stage of the magmatic intrusion,and the metallogenesis took place in the transition stage from syn-collision to post-collision in the tectonic setting of the Qinling Orogenic Belt(QOB) after continental collision be-tween the North China Block(NCB) and the South China Block(SCB).This process is also corre-sponding to the geological events of metamorphism and deformation in South Qinling,closure of the Mian-Lue oceanic basin,and exhumation of the Dabie-Sulu ultrahigh-pressure metamorphic rocks.The large-scale continent-continent collision between NCB and SCB in the middle Triassic triggered sig-nificant crustal thickening and exhumation of subducted slab.In the late Triassic,the tectonic setting was transformed to the transition stage from collision to extension.Materials from the asthenospheric mantle would ascend into the root of the lower crust,which could induce partial melting of the lower crust and generate Mo-enriched granitic magma.The ore-forming elements enriched in the fluid derived from the condensation and fraction of the magma resulted in the Mo mineralization.The Mo deposits in the QOB are mainly formed in two episodes,namely 220± Ma and 140± Ma.The two episodes of metal-logenesis were developed in the tectonic transition settings from compression to extension,but they were in the different stages of the tectonic evolution.The occurrence of the Wenquan Mo-bearing plu-ton indicates that the Triassic tectonic-magmatic belt of Western Qinling is another favorable region for Mo mineralization in the QOB.Therefore,it is significant to pay more attention to evaluation of the ore-forming potentiality in the Triassic granites in Western Qinling.ZHU LaiMin DING ZhenJu YAO ShuZhen ZHANG GuoWei SONG ShiGang QU WenJun GUO Bo LEE Ben 2009Chinese Science Bulletin2009,54,13:12
2He-Ar isotopic system of fluid inclusions in pyrite from the molybdenum deposits in south margin of North China Block and its trace to metallogenetic and geodynamic background显示文摘The helium and argon isotopic compositions of the ore-forming fluids from the molybdenum deposits such as Jinduicheng, Donggou, Shijiawan, and Sandaozhuang, which are located in the East Qinling molybdenum belt in south margin of North China Block (SMCNB), are reported in this paper. The origin and the evolution of the ore-forming fluids and their coupled-relationships with the intra-continental collision and orogenic process of Qinling Orogen in Mesozoic-Cenozoic have been discussed. The 3He/4He and 40Ar/36Ar values (3He/4He=1.38―3.64 Ra, and 40Ar/36Ar=295.68―346.39, respectively) of the fluid inclusions in pyrite from the molybdenum deposits in East Qinling suggest that, the ore-forming fluid system is mixed by two end members. One is the high temperature deep-derived fluid congenetic with the porphyries generated by crust-mantle mixing, and the other is the low-temperature meteoric water which is rich in crustal radiogenic He with the component of atmospheric Ar. From the Pb isotopic composition, and ore-bearing potential of the porphyry and the regional stratum, we can conclude that the ore-forming materials of the deposits in the East Qinling molybdenum belt are derived from the deep source by the mixing of lower crust and upper mantle. Therefore, the formation of the molybdenum deposits in SMNCB can be related to the crust-mantle interaction, which is accompanied by the intra-continental orogenic and extension process in the post-collision period of Qinling Orogen. The granitic porphyries which are related to Mo mineralization are not simple crust-remelting type granites or S type granites, but belong to syntexis-type or mantle-derived granites, hence their formation has a profound and regional geodynamic background.ZHU LaiMin ZHANG GuoWei GUO Bo LEE Ben 2009Chinese Science Bulletin2009,54,14:8
3A more consistent intraluminal rhesus monkey model of ischemic stroke显示文摘Endovascular surgery is advantageous in experimentally induced ischemic stroke because it causes fewer cranial traumatic lesions than invasive surgery and can closely mimic the pathophysiology in stroke patients. However, the outcomes are highly variable, which limits the accuracy of evaluations of ischemic stroke studies. In this study, eight healthy adult rhesus monkeys were randomized into two groups with four monkeys in each group: middle cerebral artery occlusion at origin segment(M1) and middle cerebral artery occlusion at M2 segment. The blood flow in the middle cerebral artery was blocked completely for 2 hours using the endovascular microcoil placement technique(1 mm × 10 cm)(undetachable), to establish a model of cerebral ischemia. The microcoil was withdrawn and the middle cerebral artery blood flow was restored. A reversible middle cerebral artery occlusion model was identified by hematoxylin-eosin staining, digital subtraction angiography, magnetic resonance angiography, magnetic resonance imaging, and neurological evaluation. The results showed that the middle cerebral artery occlusion model was successfully established in eight adult healthy rhesus monkeys, and ischemic lesions were apparent in the brain tissue of rhesus monkeys at 24 hours after occlusion. The rhesus monkeys had symptoms of neurological deficits. Compared with the M1 occlusion group, the M2 occlusion group had lower infarction volume and higher neurological scores. These experimental findings indicate that reversible middle cerebral artery occlusion can be produced with the endovascular microcoil technique in rhesus monkeys. The M2 occluded model had less infarction and less neurological impairment, which offers the potential for application in the field of brain injury research.Bo Zhao Guowei Shang Jian Chen Xiaokun Geng Xin Ye Guoxun Xu Ju Wang Jiasheng Zheng Hongjun Li Fauzia Akbary Shengli Li Jing Lu Feng Ling Xunming Ji 2014Neural Regeneration Research2014,9,23:6
4Geological characteristics,metallogenic background,and genesis of the Tongyu VHMS copper deposit in the west part of the North Qinling,Shaanxi Province显示文摘The Tongyu volcanic-hosted massive sulfide(VHMS) copper deposit is located in the west part of the North Qinling(NQL),Shaanxi Province.Here we report geological features and trace elemental characteristics of ores,mineralized rocks,and volcanic host rocks of this deposit.We also conducted in situ zircon U-Pb and Lu-Hf LA-ICP-MS dating and lithogeochemical study of the Meigou granodiorite,which is intruded in the south of the Tongyu mining district.It is inferred that the volcanic host rocks of the Tongyu Cu deposit belong to calc-alkaline island arc volcanic rocks,and the volcanic host rocks and the ore-forming materials share common material sources.During subduction of the Paleo-Qinling oceanic slab at around 472 Ma,high oxygen-fugacity aqueous fluid released by dehydration reaction of the subducting slab rose into the mantle wedge,leached Cu and other metal elements,and triggered partial melting of the mantle wedge.Associated with the ore-forming materials,the arc calc-alkaline magmas erupted and formed the Tongyu VHMS deposit.The weighted average zircon U-Pb age of the Meigou granodiorite is 439.3±3 Ma,suggesting its genesis is associated with the subduction event of the Paleo-Qinling oceanic plate around 440 Ma.In terms of the granitoid's geochemical characteristics,the Mg#,Ni,and Cr contents are high.REE show strongly fractionated patterns with unobvious Eu anomalies.Sr contents are high while Y contents are low,resulting in high Sr/Y ratios.Two-stage zircon Hf model ages mostly range between 908 and 723 Ma,with εHf(t)>0.Therefore,we classify Meigou granodiorite as island arc granite with adakitic geochemical features.It was generated by interaction between mantle wedge and melt produced by partial melting of the subducted basaltic slab of the Paleo-Qinling Ocean.The Tongyu VHMS deposit was formed in the island arc tectonic setting during Ordovician-Silurian between 439.3±3 Ma and 472±11 Ma.The volcanic exhalation-sedimentation,which was contemporaneous with the submarine volcanics,produced the primary mineralization of the Tongyu Cu deposit.Afterward,the ore bodies and host rocks were reworked and overprinted intensively by structures corresponding with the overall collisional orogenic process of the Qinling Orogenic Belt during the Indosinian period.In contrast to classic VHMS deposits such as the Kuroko deposit in Japan,the Tongyu Cu deposit possesses the dual characteristics of island arc volcanic exhalation and sedimentation as well as structural reworking and overprinting.Therefore,the Tongyu VHMS Cu deposit is a volcanic exhalation and sedimentation-structural reworking and overprinting type deposit.Ben Lee LaiMin Zhu GuoWei Zhang Bo Guo HuJun Gong AnPing Yao 2010Science China Earth Sciences2010,53,10:5
5Room-Temperature Phosphorescent Organic-Doped Inorganic Frameworks Showing Wide-Range and Multicolor LongPersistent Luminescence显示文摘Long-persistent luminescence based on purely inorganic and/or organic compounds has recently attracted much attention in a wide variety of fields including illumination,biological imaging,and information safety.However,simultaneously tuning the static and dynamic afterglow performance still presents a challenge.In this work,we put forward a new route of organic-doped inorganic framework to achieve wide-range and multicolor ultralong room-temperature phosphorescence(RTP).Through a facile hydrothermal method,phosphor(tetrafluoroterephthalic acid(TFTPA))into the CdCO_(3)(or Zn_(_(2))(OH)_(2)CO_(3))host matrix exhibits an excitation-dependent colorful RTP due to the formation of diverse molecular aggregations with multicentral luminescence.The RTP lifetime of the doped organic/inorganic hybrids is greatly enhanced(313 times)compared to the pristine TFTPA.The high RTP quantum yield(43.9%)and good stability guarantee their easy visualization in both ambient and extreme conditions(such as acidic/basic solutions and an oxygen environment).Further codoped inorganic ions(Mn_(2)+and Pb_(2)+)afford the hybrid materials with a novel time-resolved tunable afterglow emission,and the excitation-dependent RTP color is highly adjustable from dark blue to red,covering nearly the whole visible spectrum and outperforming the current stateof-the-art RTP materials.Therefore,this work not only describes a combined codoping and multicentral strategy to obtain statically and dynamically tunable long-persistent luminescence but also provides great opportunity for the use of organicinorganic hybrid materials in multilevel anticounterfeiting and multicolor display applications.Guowei Xiao Bo Zhou Xiaoyu Fang Dongpeng Yan 2021Research2021,,1:4
6Hydrogen-bonded network: An effective approach to improve the thermal stability of organic/polymer electro-optic materials显示文摘Preparation of PMMA-co-PHPMN-(4-hydroxyphenyl)maleimide was prepared according tothe literature [1]. The monomer mixtures, comprising of 0.6g N-(4-hydroxyphenyl)maleimide, 0.4 g MMA and 0.004 g , ′-azobisisobutyronitrile (AIBN) were dissolved in 2 mLDMF. Air above the monomers was swept out using thefreeze-pump-thaw procedure three times and filledDENG GuoWei BO ShuHui ZHOU TingTing ZHANG Rong LIU JiaLei LIU XinHou ZHEN Zhen QIU Ling 2013Science China Chemistry2013,56,2:1
7Geochemistry of the Jinduicheng Mo-bearing porphyry and deposit, and its implications for the geodynamic setting in East Qinling, P.R. China显示文摘Laimin Zhu Guowei Zhang Bo Guo Ben Lee Hujun Gong Fei Wang 2009Chemie der Erde - Geochemistry - Interdisciplinary Journal for Chemical Problems of the Geosciences and Geoecology2009,,2:1
8Influence of semi-solid isothermal treatment on eutectic carbide in Cr12MoV steel显示文摘In-situ observation of eutectic solidification of Cr12MoV steel was conducted using high temperature confocal laser-scanning microscopy. The semi-solid isothermal treatment temperature of the steel was determined by thermodynamic calculation using Thermo-cal software. At the same time, the infl uences of isothermal treatment temperature and time on eutectic carbides in the steel were also studied. The results show that when the liquid metal cools at the rate of 47 °C·min-1, the eutectic reaction occurs rapidly at 1,214.7 °C in one second with the reticular liquid around austenite dendrites, transforming into a network of eutectic structure. After being held at 1,300 °C for 30 min, the carbide network is broken due to the impingement of refi ned primary austenite dendrites and secondary dendrites arms, and the thickness of eutectic structure is reduced.Li Qingchun Yang Bo Li Chong Wang Chao Chang Guowei 2014China Foundry2014,11,6:1
9Unravelling the precipitation evolutions of AZ80 magnesium alloy during non-isothermal and isothermal processes显示文摘The precipitation evolutions of Mg-Al-Zn alloys play essential roles in their mechanical properties,corrosion performance,formability,plastic deformation mechanisms and texture development.In the present work,the precipitation evolutions of AZ80 magnesium alloy during both non-isothermal and isothermal processes were unraveled by utilizing in situ electrical resistivity monitoring,hardness testing,differential scanning calorimetry and microstructural characterization.The results showed that discontinuous precipitation(DP)and continuous precipitation(CP)occurred competitively during non-isothermal and isothermal processes.The precipitation of dominantβ-Mg17 Al12 phase during non-isothermal processes was highly dependent on the thermal history.During isothermal processes,the precipitation behavior of AZ80 magnesium alloy could be considered as the functions of holding temperature and time.At lower temperatures,massive DP and CP were gradually formed to equally strengthen the alloy.At higher temperatures,the Ostwald coarsening was characterized in the later stages and indicated to slightly soften the alloy.Isothermal time-temperature-precipitation curves and quantitative precipitate evolution were estimated to unravel precipitation characteristics and their strengthening functions.Longqing Tang Guowei Bo Fulin Jiang Shiwei Xu Jie Teng Dingfa Fu Hui Zhang 2021Journal of Materials Science & Technology2021,,16:1
10A Key Technique of Coupling SWAT with Web GSI Platform: A Case Study of the Longgang River Basin显示文摘Via field investigation and data collection in the Longgang River basin, input data for SWAT watershed hydrological model were obtained. Sub-basin s boundary was calculated and divided by spatial analysis, and meteorological input conditions were used to drive example simulation, such as rainfall and temperature. Watershed database was established in the backend of server, and GIS resources were provided by issuing GIS service, and WebGIS platform was developed in front of the browser. Executive file was generated by compiling source file of SWAT model, and input file and parameter modification, model operation and calculation, and result extraction and transmission were conducted via PHP, to realize the coupling of SWAT model with WebGIS platform, and enhance display effects of model input conditions and simulation results.Liao Guowei Xie Linshen Chen Chunxing Chen Bo Zhang Leidong 2019Meteorological and Environmental Research2019,10,4:0
11Unraveling precipitation evolution and strengthening function of the Al-Zn-Mg-Cu alloys with various Zn contents:Multiple experiments and integrated internal-state-variable modeling显示文摘Zn content is one of the most concerned factors in the development of next generation ultra-strength Al-Zn-Mg-Cu alloys owing to its essential role in precipitation strengthening.In the present work,the underlying functions of Zn content in precipitation evolution and strengthening function of Al-Zn-Mg-Cu alloys were systematically investigated by combining multiple experiments and an integrated internalstate-variable model.The experimental results indicated that the increased Zn content in Al-Zn-Mg-Cu alloys would promote the development of precipitates and enhance aging hardening.The diffusion flux of soluble Zn and the coordination of Mg atom controlled the crystallographic microstructures evolution during precipitates nucleation,growth and transition processes.By integrating precipitation development with electrical resistivity and hardness evolutions,an improved internal-state-variable physical model was then developed for the aging responses of Al-Zn-Mg-Cu alloys.The unified model considered the intrinsic characteristics of precipitates such as crystallographic orientation,morphology,component,and distribution.The specific improvements were to balance the combined functions of Zn element and Mg element and consider the plate-like morphology and directed growth as indicated by experiments.This model was also adaptive to heat-treatment variables and chemical compositions,and owned the notable advantages to simultaneously rationalize the observed microstructural characteristics,mechanical and electrical properties following artificial aging of Al-Zn-Mg-Cu alloys.In addition,a preliminary model framework between electrical resistivity and hardness for Al-Zn-Mg-Cu alloys was established.Jie Tang Mingcai Liu Guowei Bo Fulin Jiang Chunhui Luo Jie Teng Dingfa Fu Hui Zhang 2022Journal of Materials Science & Technology2022,,21:0
12Expert consensus on blood pressure management in critically ill patients显示文摘Introduction For critically ill patients with unstable hemodynamics,goal‑directed therapy for arterial blood pressure is needed with continuous daily bedside monitoring.The prevalence of hypertension in Chinese adults is 25.2%,of which 1–2%of patients may experience a hypertensive emergency,with a mortality rate of 6.9%in the acute phase.The mortality and readmission rates within 90 days of onset are as high as 11%.[1]Furthermore,the mortality rate for patients who experience hypertensive emergencies can reach 50%within 12 months of the incident.[2]The incidence of perioperative hypertension in patients undergoing cardiac surgery is approximately 50%,with this figure dropping to 25%for non-cardiac surgery.Surgery may increase the incidence of perioperative cardio-cerebrovascular adverse events by 3–5%.[3]Yuetian Yu Ye Gong Bo Hu Bin Ouyang Aijun Pan Jinglun Liu Fen Liu Xiu-Ling Shang Xiang-Hong Yang Guowei Tu Changsong Wang Shaolin Ma Wei Fang Ling Liu Jiao Liu Dechang Chen 2023Journal of Intensive Medicine2023,3,3:0
13Resource assessment for combined offshore wind and wave energy in China显示文摘The development of offshore wind farms has experienced rapid growth during the past decade. In particular, China has the highest number of installations worldwide, but some challenges exist for further development. Consequently, some researchers suggest combining wave energy with offshore wind energy. To fully implement this plan, a comprehensive resource assessment of combined offshore wind and wave energy systems is needed. Investigations of the parameters, such as the spatial and temporal distribution of wind and wave energy, aggregate resource reserves, available technical potential, and total capacity factor, are vital for designing the required wind turbines and wave energy converters. To assist scientific development and governmental decision making, this paper aims to evaluate offshore wind and wave energy resources from a technological perspective. The results show that theoretical offshore wind and wave energy resources are abundant in China's ocean territory, with a potential of approximately 3 TW. Technically, of the three most popular offshore wind turbines, i.e., 6, 8, and 10 MW, 10 MW is overall the most suitable in China. However, of the three wave energy converters, i.e., 120, 250, and 750 kW, 120 kW is the best candidate for Liaoning Province, and 750 kW is the most suitable for the remainder of its region. Overall, the total annual energy production is approximately 7000 TWh.JIANG Bo HOU ErHu GAO ZhiTeng DING Jie FANG YiZhou KHAN Salman S. WU GuoWei WANG Qiang MENG FanTai LI Ye WANG XiaoYong 2023Science China(Technological Sciences)2023,66,9:0
14Designable heteronanocrystals via interface redox reaction显示文摘The synergistic interaction of different components in heteronanocrystals induces interfacial phenomena and novel functionalities.Nonetheless,effective technologies to design and fabricate heteronanocrystals with materials on demand are still missing.Rich heterostructures in a copper patina are known to form at room temperature and under atmospheric pressure.The redox process of copper tarnish inspired the discovery of a simple strategy to achieve heteronanocrystals that contained elements from group 3-11 and group 14-16.The interface redox-induced method is self-regulating at ambient conditions and applicable for metal,semiconductor,and dielectric materials.The enhanced interface bonding endows the heteronanocrystals with outstanding stability and catalytic performance,while the modular approach enables the design and fabrication of heteronanocrystals with intended materials to meet different purposes.Zhihua Li Yang Li Nannan Luo Yuanyuan Qie Dingyi Yang Guowei Cao Yuxiang Liu Ying Fu Na Li Wen Hu Min Zhang Rusen Yang Bo Tang 2023Nano Research2023,16,4:0
15Online Inertia Estimation Using Electromechanical Oscillation Modal Extracted from Synchronized Ambient Data显示文摘An ambient modal framework for inertia estimation using synchrophasor data is proposed in this letter.Specifically,an analytical formulation is developed for the estimation of inertia based on the frequency and damping ratio modes extracted from ambient data.An advantage of the proposed framework is that it can rely on synchronized ambient data under non-disturbed conditions for online estimation and tracking of inertia.Ultimately,numerical simulation studies and physical experiments demonstrate the feasibility of the proposed approach.Bo Wang Deyou Yang Guowei Cai Jin Ma Zhe Chen Lixin Wang 2022Journal of Modern Power Systems and Clean Energy2022,10,1:0
16Modular Synthesis of Tetraurea and Octaurea Macrocycles Encoded with Specific Monomer Sequences显示文摘Intermolecular hydrogen bonding among urea units grants prominent mechanical strength to polyurea elastomer materials.However,such interactions can cause significant solubility problems when synthesizing oligourea macrocycles with a large number of urea units,and it remains unknown for macrocycles containing more than six urea units.Here,we demonstrate a two-step,modular strategy for making a new class of tetraurea and octaurea macrocycles using commercially available building blocks.Intramolecular hydrogen bonding within the fundamental o-phenylene bis(urea)unit is the key to overcoming intermolecular hydrogen bonding to form favorable conformations for ring-closure reactions.The size and monomer sequences can be controlled by varying the flexibility of the spacers.Rigid diphenyl methylene and diphenyl ether linkers selectively afford tetraurea macrocycles,whereas the flexible hexylene linker produces octaurea macrocycles.Macrocycles encoded with two different spacers were also made.All these macrocycles are confirmed by X-ray diffraction structural analysis of the complexed forms with sulfate anions.Interestingly,a unique“figure-eight”structure is observed for the complex of MUH octaurea macrocycle with two encapsulated sulfate anions.Our study shows a paradigm of making large oligourea macrocycles with designer properties in a programable manner with tunable monomer sequences.Guowei Zhao Si-Qi Chen Wei Zhao Boyang Li Wenyao Zhang Bo Zheng Xiao-Juan Yang Biao Wu 2022CCS Chemistry2022,4,7:0
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